1-Ammonionaphthalene-2-sulfonate
نویسندگان
چکیده
In the mol-ecule of the zwitterionic title compound, C(10)H(9)NO(3)S, an intra-molecular N-H⋯O hydrogen bond results in the formation of an almost planar six-membered ring (r.m.s daviation = 0.0150 Å), which is oriented at a dihedral angle of 1.63 (3)° with respect to the naphthalene ring system. In the crystal structure, inter-molecular N-H⋯O hydrogen bonds link the mol-ecules into a two-dimensional network.
منابع مشابه
8-Ammonionaphthalene-2-sulfonate monohydrate: the zwitterionic hydrate of 1,7-Cleve’s acid
The structure of 8-amino-2-naphthalene-sulfonic acid monohydrate (1,7-Cleve's acid hydrate), C(10)H(9)NO(3)S·H(2)O, shows the presence of a sulfonate-aminium group zwitterion, both groups and the water mol-ecule of solvation giving cyclic R(3) (3)(8) O-H⋯O and N-H⋯O inter-molecular hydrogen-bonding inter-actions, forming chains which extend down the a axis of the unit cell. Additional periphera...
متن کاملSolvent effect on ion-pair extraction of 2-(2-pyridylazo)-1-naphthol-4-sulfonate anion with solvated hydroxonium ion using alcohols and 1-octanol/octane mixed solvents.
Extraction of 2-(2-pyridylazo)-1-naphthol-4-sulfonate anion with solvated hydroxonium ion was carried out using 14 kinds of alcohols and 1-octanol/octane mixed solvents as a solvent at 25 degrees C. Alcohols are 1-pentanol, 1-hexanol, 1-heptanol, 2-heptanol, 3-heptanol, 4-heptanol, 1-octanol, 2-octanol, 3-octanol, 1-nonanol, 2-nonanol, 3-nonanol, 5-nonanol and 1-decanol. Among them, 1-octanol w...
متن کاملRing opening at N1-C2 bond of azetidin-2-ones by a molybdenum hydroxo-carbonyl complex: evidence from a computational study.
Computations on the reaction of azetidin-2-one, N-sulfonate azetidin-2-one, and 3-formylamine-N-sulfonate azetidin-2-one with [Mo(OH)(eta3-C3H5)(CO)2(N2C2H4)] were performed at the B3LYP/6-31+G(d,p) (LANL2DZ for Mo augmented by f polarization functions with exponents 1.043) taking into account solvent effects by means of the PCM-UAHF model. According to our calculations, the rate-determining en...
متن کاملR22(8) motifs in Aminopyrimidine sulfonate/carboxylate interactions: Crystal structures of pyrimethaminium benzenesulfonate monohydrate (2:2:1) and 2-amino-4,6-dimethylpyrimidinium sulfosalicylate dihydrate (4:2:2)
BACKGROUND Pyrimethamine [2,4-diamino-5-(p-chlorophenyl)-6-ethylpyrimidine] is an antifolate drug used in anti-malarial chemotherapy. Pyrimidine and aminopyrimidine derivatives are biologically important compounds owing to their natural occurrence as components of nucleic acids. RESULTS In the crystal structures of two organic salts, namely pyrimethaminium benzenesulfonate monohydrate 1 and 2...
متن کاملModified CNTs/Nafion composite: The role of sulfonate groups on the performance of prepared proton exchange methanol fuel cell’s membrane
A novel Nafion®-based nanocomposite membrane was synthesized to be applied as direct methanol fuel cells (DMFCs). Carbon nanotubes (CNTs) were coated with a layer of silica and then reacted by chlorosulfonic acid to produce sulfonate-functionalized silicon dioxide coated carbon nanotubes (CNT@SiO2-SO3H). The functionalized CNTs were then introduced to Nafion®, and subsequently, methanol permeab...
متن کامل